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Angelina Jolie in SaltAngelina Jolie: tomb raider, assassin and world-class beauty...

Whether dazzling audiences with her breathtaking breakout in 'Gia,' assuming her rightful place as "Sexiest Woman Alive" on Esquire's November 2004 cover or walking the red carpet with Brad Pitt, Angelina Jolie never ceases to awe with her beauty.

And now she's back with a brand-new, ass-kicking movie, Salt, with Jolie as a slick CIA agent who's accused of being involved in a plot to assassinate the president and is forced to clear her name - and stop the plot.

In a pictorial homage, Moviefone looks back at 20 of Angie's most jaw-dropping, eye-defying, downright sexiest moments ever.

Take a look after the jump... Angelina Jolie in SaltAngelina Jolie: tomb raider, assassin and world-class beauty...

Whether dazzling audiences with her breathtaking breakout in 'Gia,' assuming her rightful place as "Sexiest Woman Alive" on Esquire's November 2004 cover or walking the red carpet with Brad Pitt, Angelina Jolie never ceases to awe with her beauty.

And now she's back with a brand-new, ass-kicking movie, Salt, with Jolie as a slick CIA agent who's accused of being involved in a plot to assassinate the president and is forced to clear her name - and stop the plot.

Click on the gallery below and enjoy the sizzling hot pictorial moments that defined Ms Jolie's career...